Caffeine by Grade

GradeCaffeine specificationPer 200 mg of extractPer 400 mg of extract
Standard grades: 45% and 50% chlorogenic acidsNot more than 5.0%, declared per batchUp to 10 mgUp to 20 mg
Reference batch: 45% grade, 46.8% CGA (CoA SVB-COA-GC45-0526-01)3.6% found7.2 mg14.4 mg
Decaffeinated 45% grade0.5% or lessUp to 1 mgUp to 2 mg
Reference batch: decaf 45% grade, 45.9% CGA (CoA SVB-COA-GCD45-0326-01)0.4% found0.8 mg1.6 mg

The per-serving figures are arithmetic. Multiply the milligrams of extract per serving by the caffeine percentage and divide by 100. Use the specification limit when you set a label figure with a safety margin. Use the batch result on the certificate when you need the actual figure for a lot. A caffeine-controlled grade with a defined target is also available for formulas that declare a precise total.

Why the Figure Varies

The species matters first. Robusta (Coffea canephora) beans naturally carry more caffeine than arabica (Coffea arabica), as surveys of both species’ accessions have shown (Ky and colleagues, Food Chemistry, 2001). Most commercial green coffee extract is made from robusta. Next comes the process. Water and water-ethanol extraction carry caffeine into the extract with the chlorogenic acids, and any purification step toward a higher chlorogenic acid figure can raise or lower it. That is why caffeine is a separate specification line. You cannot read it off the chlorogenic acid percentage.

How Caffeine Is Measured

Caffeine is measured by HPLC with UV detection. ISO 20481:2008 is the international HPLC method for caffeine in coffee and coffee products, and its scope includes green coffee and decaffeinated products. Ask that the certificate name the method, and that caffeine is reported from the same HPLC run as the chlorogenic acids where the laboratory does both. For how the chlorogenic acid figure itself is measured, see green coffee extract HPLC standardisation.

Intake Reference Points

The European Food Safety Authority’s 2015 scientific opinion on the safety of caffeine reached three conclusions:

At the standard-grade limit of 5.0%, 200 mg of caffeine would take 4 g of extract. Supplement servings are far smaller. In practice the caffeine figure matters for three things: the label, “caffeine-free” or evening-use positioning, and combination products that already contain caffeine from another source, where the totals add up.

Choosing a Grade

All three are specified on our green coffee bean extract page, with caffeine reported on every certificate. For specification and documents more broadly, see the green coffee bean extract buyer’s guide. If you are choosing between the two caffeine-bearing extracts, compare them in green coffee vs green tea extract and caffeine in green tea extract by grade.